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Mercury (element)

Mercury, also called quicksilver, is a chemical element in the periodic table that has the symbol Hg (from the Latin hydrargyrum, for watery (or liquid) silver) and atomic number 80. A heavy, silvery, transition metal, mercury is one of five elements that are liquid at or near room temperature (the others are the metals caesium, francium, and gallium, and the nonmetal bromine). more...

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Mercury is used in thermometers, barometers and other scientific apparatuses, although the use of mercury in thermometers has been largely phased out in clinical and scientific environments (in favor of alcohol-filled, digital or thermistor-based replacements) in the interests of health and safety due to the toxicity of the element. Mercury is mostly obtained by reduction from the mineral cinnabar. Its high density allows things such as billiard balls to float with less than 20% of their volume submerged.

Applications

Mercury is used primarily for the manufacture of industrial chemicals or for electrical and electronic applications. It is used in some thermometers, especially ones which are used to measure high temperatures (In the United States, non-prescription sale of mercury fever thermometers was banned by a number of different states and localities). Other uses:

  • Mercury sphygmomanometers.
  • Thimerosal, an organic compound used as a preservative in vaccines and tattoo inks (Thimerosal in vaccines).
  • Mercury barometers, diffusion pumps, coulometers, and many other laboratory instruments. As an opaque liquid with a very high density, it is ideal for this role
  • The triple point of mercury, -38.8344 °C, is a fixed point used as a temperature standard for the International Temperature Scale (ITS-90).
  • In some gaseous electron tubes, mercury arc rectifier
  • Gaseous mercury is used in mercury-vapor lamps and some "neon sign" type advertising signs and fluorescent lamps.
  • Liquid mercury was sometimes used a coolant for nuclear reactors. However sodium is proposed for reactors cooled with liquid metal, because the high density of mercury requires much energy for circulating the coolant.
  • Mercury was once used in the amalgamation process of refining gold and silver ores. The practice is continued by the garimpeiros (gold miners) of the Amazon basin in Brazil.
  • Mercury is still used in some cultures for folk medicine and ceremonial purposes which may involve ingestion, injection, or the sprinkling of elemental mercury around the home.
  • Alexander Calder built a mercury fountain for the Spanish Pavilion at the 1937 World's Fair in Paris.

Miscellaneous uses: mercury switches, mercury cells for sodium hydroxide and chlorine production, electrodes in some types of electrolysis, batteries (mercury cells), and catalysts, herbicides (discontinued in 1995), insecticides, dental amalgams/preparations and liquid mirror telescopes.

Historical uses: preserving wood, developing daguerreotypes, silvering mirrors, anti-fouling paints (discontinued in 1990), cleaning, and in road leveling devices in cars. Mercury compounds have been used in antiseptics, laxatives, antidepressants, and antisyphilitics. It was also allegedly used by allied spies to sabotage German planes. A mercury paste was applied on bare aluminum, causing the metal to rapidly corrode. This would cause the planes to mysteriously fall apart. In Islamic Spain it was used for filling decorative pools and for fountains .

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Mercury in saliva and the risk of exceeding limits for sewage in relation to exposure to amalgam fillings
From Archives of Environmental Health, 7/1/02 by Jorma Leistevuo

HEAVY-METAL MERCURY (Hg) is a toxic element. It is also a bactericidal agent among other antimicrobial agents, such as penicillin, sulfa, and tetracycline. Dental amalgam fillings contain approximately 50% mercury, (1) and it is widely accepted that such fillings can release mercury into the environment. (2-14) In bacteria, the genes for mercury resistance and antimicrobial resistance are found together. (13,15,16) Resistant bacteria are widespread in the environment (17,18) and can cause severe difficulties when infections are treated with antimicrobial agents. Furthermore, the environmental load of mercury, including that released from amalgam fillings, may promote and maintain both antimicrobial resistance and mercury resistance. (11) All factors and possible routes that facilitate the development of antimicrobial-resistant organisms need to be considered. Therefore, a more profound understanding is needed of factors affecting the discharge of mercury into the environment.

In the present article, the authors examined mercury in human saliva as a pollutant. The authors used odds ratios (ORs) to calculate the risk of exceeding the mercury limits for sewage in relation to exposure to dental amalgam "silver" fillings.

Materials and Method

Subjects. All study subjects (N = 187) were adult Finnish outpatients from the Students' Health Care Center at the University of Turku and from 3 private dental surgical practices (mean age = 43 yr, range = 19-83 yr; women = 62%, men = 38%). Patients with no exposure to dental amalgam fillings who visited the Students' Health Care Center on 2 predetermined days each week were also invited to participate in the study. We selected the names of the study subjects from the data banks of 3 private dental surgery practices by repeatedly drawing a random letter of the alphabet, and 10 consecutive subjects whose 1st letter of his or her last name matched the randomly selected letter were invited to participate. This procedure was repeated until a sufficient number of patients had been selected. We divided the subjects into 3 groups: the NAR group (n = 56), which contained individuals who had had their amalgam fillings removed (mean time since last removal = 390 days); the NA group (n = 43), which contained individuals who had never been exposed to dental amalgam fillings; and the A group (n = 88) comprising individuals who had various numbers of amalgam fillings. The characteristics of each group are given in Table 1.

Saliva samples and dental amalgam filling status. Special emphasis was placed on preventing mercury contamination during the study, and all study materials were tested for mercury traces prior to use. To standardize sampling, a paraffin-stimulated 5-mi whole-saliva sample was collected, and the dental amalgam filling status was recorded by the same experienced dentist (JL), who consistently used the same protocol. An amalgam-filled surface was defined as an amalgam filling that exceeded one-half of the area of the tooth surface.

Determination of total mercury content in saliva. The whole-saliva samples were frozen within 3 hr of collection and sent for analysis to the Oulu Regional Institute of Occupational Health, Oulu, Finland. Total mercury content (inorganic and organic) was determined by cold-vapor atomic absorption spectrometry (Varian Techtron, SpectrAA-400, Varian Associates [Sunnyvale, California]), in accordance with a modified version of the method described by Magos and Cernik. (19,20) This method can identify mercury concentrations as low as 1 nmol/l.

Statistical methods. We used logarithmic transformation to correct the skewed distribution of total mercury concentrations. The Hosmer and Lemeshow goodness-of-fit test approximated the fitness of the model. Fisher's exact test (2-tailed) examined the significance of the differences among the study groups. The groups were compared with the assistance of logistic models (21) in terms of the proportions of study subjects' saliva that exceeded the upper limit for mercury in sewage. We calculated ORs and 95% confidence intervals (CIs) to quantify the differences. Values of p less than .05 were interpreted as being statistically significant. Statistical calculations were performed with the SAS statistical program package (SAS System for Windows, release 6.12/1996).

Ethical approval. This study was approved by the Ethical Committee of Turku University.

Results

Concentration of total mercury in saliva. We found statistically significant (p = .001) higher total mercury concentrations in paraffin-stimulated saliva from the amalgam (A) group than from the nonamalgam groups (NA and NAR). The average level of mercury in the A group (i.e., 174 nmol/I) was 23 times higher than in the combined nonamalgam groups (i.e., 7.5 nmol/I). The NA and NAR groups had almost equal mercury levels in paraffin-stimulated saliva (Table 2).

Relation of total mercury in saliva to number of amalgam-filled surfaces. The association between mercury in saliva and the number of amalgam-filled surfaces was studied in subjects with 1 or more amalgam-filled surfaces. Given the skewed distribution, the data were logarithmically transformed. Following transformation, the shape of distribution closely approximated a normal distribution (p = .942). A clear and statistically significant ascending linear trend was observed for the association between the number of amalgam-filled surfaces and the logarithm of total mercury in saliva (p = .011) (Fig. 1). The estimated regression equation was as follows: logarithmic value of total mercury in saliva = 3.27 + 0.05 x no. amalgam-filled surfaces (95% CI [slope of the trend] = 0.026, 0.066).

[FIGURE 1 OMITTED]

Probability of exceeding the upper limit for mercury in sewage. In the A group, the limits for mercury in sewage were exceeded quite frequently. The council directive of the European Economic Community (84/156/EEC) specifies a limit of 0.05 mg/l (i.e., 250 nmol/l) effluent "on values and quality objectives for mercury discharges by sectors other than the chlor-alkali electrolysis industry." (22) This limit is used in the Finnish town of Turku, whereas in the capital--Helsinki--a limit of 50 nmol/l is used. (23) None of the nonamalgam groups exceeded thN PROCESS IN EASTERN AND CENTRAL EUROPE. Edited by Jurgen Rose & Johannes Ch. Traut. Hamburg, Germany: LIT Verlag. 2001. Pp. vii, 372. Cloth, $65.

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